At the 64th Annual Venice Film Festival on September 2, 2007, Hollywood power couple Angelina Jolie and Brad Pitt graced the premiere of “The Assassination of Jesse James by the Coward Robert Ford” in Venice, Italy. The red carpet event showcased the couple’s undeniable charisma and star power, drawing attention from fans and media alike. Dressed in stylish ensembles, Jolie and Pitt exemplified elegance, creating a memorable moment amid the glamour of the prestigious film festival. The Venice premiere marked a time when the couple frequently captivated audiences with their joint appearances, adding to their status as one of Hollywood’s most iconic pairs.